living in Texas, the pond is probably not prone to freezing, so the that shouldn't be a problem.
If you want to keep anything live in the pond, you're going to need a filter of some kind. A skimmer box with a pump into a filter tank, and on to a water fall would be perfect.
Anyway, in a 100G outdoor pond, assuming you do add a filter, you could keep 4 or 5 comet, subunkin, or sarasa goldfish. No fancy goldfish or koi. You could also keep rosy red minnows or white cloud minnows.
One last thing to consider - if the pond is exposed to the sun, the small amount of water you have is going to get very hot very fast. I would recommend putting some kind of covering over - like a pergola, or similar, AND add some floating plants to let the fish hide from birds and other animals.